The MPA-S250NC is a different (and slightly more affordable) design than the MPA-S250NC, even if both use the same integrated Ncore PSU and amplifier module. In particular, the case work is obviously more compact and more simplistic, and you have to choose between XLR and RCA inputs (the latter being appropriate for the Ultra).
The trigger is most likely implemented identically but so far nobody has answered the question how well this works with the Ultra.
@campaz, any amplifier being able to push >= 60 W into 4 ohms will be able to drive the Diva 262 to their sound pressure limits. And the NC252MP will provide all the low distortion and output impedance you could ask for.
If your unsure about the trigger in combination with the WiiM Ultra it's probably best to ask Audiophonics directly. They should know best, because they do sell WiiM, too.