So, you have (at least) three different places you can control the volume? That makes it
potentially more difficult.
The output level of the WiiM Ultra's subwoofer output will always be directly proportional to the level of it's stereo output in use, be it the line output or any.digital.output. You can control the ratio by setting the subwoofer level from -15 dB to + 15 dB, but that's it. This ratio almost for sure
must be set differently when using line out vs. a digital out.
If you don't want to share your system details or how you're listening to Room that's all fine. But I'm this case we can only give generalised advice, you'll have to evaluate for yourself.