I just stuck it into Gemini and asked and this is the response I got so I guess they're saying it's not possible.
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I think the only way I'll be able to do it is with an audio interface that has software you install on your PC that then integrates with the Windows volume control, something like this
I used to have a Focusrite Sapphire 40 Pro and used it to mix the USB from my computer with the optical in from a WiiM and then out to my amp but they stopped updating the firmware so it became incompatible unfortunately