You would still have to manage the delay on another device than the Wiim, because you are not using its Sub-Out output, so how would it be able to add any delays adjustments?
Maybe if you can set the delay in the DSpeaker it would work, you could then just do the measurement ("Audio Sync" in Wiim app, NOT "Subwoofer &Speakers Sync") by first disabling the Sub that is connected to your DSpeaker, and measuring the delay for L-R speakers only, write that value down (By entering the "Audio Synch"- menu again and choosing "Manual" you can see the currently set/measured value).
Then turn off the L-R speakers and turn on the SUB, do the measurement again and get that value the same way as above, write it down.
Enter the delay you got using the Wiim into the DSpeaker.
Since you do not need the delay value for the Sub in Wiim, re-enter the value you got from measuring only the L-R Speakers again!
Perform above measurements again, they (L-R and Sub speakers) should now have the same value measured in Wiim, or adjust in DSpeaker until they match.
This could work